INTRODUCTION
This booklet
is a quick reference guide to the capabilities of Dyman Foams range of
Industrial Foam Products. It is designed to expand upon the standard specification booklet and provide more information on product production and end uses.
The
Technical Department is continually upgrading the performance
specifications for all our products. Where details of performance or fire tests are
required they can be obtained upon request.
All the
products listed in this booklet are standard stock lines readily available for
distribution through all our offices Australia wide. Please read the document
in conjunction with a foam catalogue. If
you require further information on a customer enquiry, in the first
instance ask the assistance of Chris Houghton,
and if you still need help, the
Technical Department or the Market Development Manager will be happy to assist.
TYPES
OF FLEXIBLE POLYURETHANE FOAM
Flexible
polyurethane foams are open cell foams expanded mainly by carbon dioxide
produced by the reaction of water and isocyanate and arc considered to be the
most important class of polyurethanes. They are used as upholstery in
furniture, as carpet underlay, in bedding and in vehicle manufacture and as
energy absorbing padding for the protection of goods and people.
The main
types of flexible foam produced by Dyman Foams may be divided into polyester
and polyether based slabstock foam. There are also a number of specialised foam grades manufactured which are utilised in a wide range of applications.
The terms
"ester" and "ether" indicate that the foams employ a polyol
with a particular combination of atoms which give the product distinct
characteristics.
Flexible
polyurethane slabstock is made in three main conventional types;
a) foams based on polyester polyols
b) foams based on conventional polyether polyols
c) high resilience foams based on modified
polyether polyols.
The properties of the polyester based, polyether based and high resilience types of flexible foams differ widely because of their difference in chemical structures. The stiffer polyester based foams having more polar carbonyl group hydrogen bonded
chains than those. of polyether. chains, have a greater resistance to both tensile and compression loads and much lower resilience than polyether based foam. The more random chemical structure of high resilience .. foams,
combined with their more irregular physical form, yields the highest resilience together with lower resistance to deformation.
Both types
of polyether based foams are more resistant to hydrolysis than the polyester based foams and this property
is important in hot, humid conditions or in the presence of acids or alkalies where the service life of
polyether foams may be in the order of ten times than those based on polyester.
Polyesters
have significantly better resistance to oxidation and to many solvents, the
latter being the main reason for their continuing use in textile and clothing
applications
Just over
90% of all flexible foam slabstock produced by Dyman Foams Group is based on
polyether polyols, with 81% of this figure being conventional flexible foam. The remainder includes polyester,
high resilience foams, super soft foams, high load bearing and specialised foams, including
sound absorbing and reticulated foams.
TERMS
FOR FOAM PROCESS CONTROL
Flexible
foam quality is checked by measuring the physical properties of the foam, using
standardised methods of measurement on standard test samples cut from the items to be checked. Our laboratory
checks the performance of each and every production run to ensure that the product meets pre-determined standards of quality and grade
specifications.
The test
results are evaluated against specified
limiting values, which experience has shown to yield satisfactory service
performance.
Many
standard tests for flexible polyurethane foams have been devised by various
national standard organisations such as the BSI in the UK, DIN in Germany, ASTM
in USA and NF in France.
In Australia
most testing is done in accordance with the Standards Association of Australia using Australian Standard 2282
(AS2282) - Method for Testing Flexible Cellular Polyurethane.
The
following brief descriptions of the test methods for measuring the physical properties are intended only to outline the principle of
the methods.
DENSITY
This is
simply a measure of the mass per unit volume and expressed in kg/m3.
Density, (as
mentioned elsewhere) is not necessarily related to hardness as it is possible to produce a super soft
flexible foam, a semi-rigid foam and a rigid foam, all of the same density.
The density
of a flexible foam must be regarded as a guide to its durability (or quality),
particularly in regard to the rate and extent of its hardness and height loss in actual service
conditions.
High density
foams are more expensive as they require more raw material for a given volume of foam.
HARDNESS
In the
majority of situations the choice of foam for a given application is primarily
decided on hardness, which in turn is related to consumer preference.
All foam
runs are tested for load bearing (hardness) and the grading of foam is partly
based on this property.
In the
AS2282 - "Method for Determining the Indentation Force on
Deflection", a flat circular indentor of 200mm diameter is mounted by a
ball joint and driven at a constant specified vertical rate to produce the specified indentation of the
sample.
The sample
is reflexed twice to 75% indentation. Then after testing the indentation force
is measured at 25%, 40%, 65% and 25%
indentation with a 60 second dwell at each point.
The IFD at
40% deflection is used (in conjunction with the density of the foam), to
classify the foam because it relates to the level which most foams are normally
compressed when used for cushioning.
Hardness
loss is a characteristic of all foams and is particularly evident in low density foams. The hardness loss can be
around 10% for heavy duty foams to 40-50% for light duty foams.
Also the
amount of hardness loss is dependent on the application, for example, a chair
back is not subjected to as much compressive stress as the chair cushion and as
a result it will not soften to the same
extent.
INDENTATION FACTOR
Also known
as the Sag factor, comfort factor, is a ratio of the 25% and 65% (65%/25%) readings. The higher ratios indicate a wider difference in the
two readings and indicate "surface
softness and deep down firmness".
COMPRESSION SET
Compression
set is a measure of the permanent deformation resulting from a fixed
compression for a given time period.
It is
expressed as the percentage loss of the foam. Sample's original thickness
and is an attempt to provide a measure of the height loss under service
conditions.
TENSILE STRENGTH AND ELONGATION AT BREAK
The test
provides a measure of the strength characteristics of a foam at breaking point. The tensile strength and
elongation properties of a foam must be adequate to allow safe handling in
manufacture and in end-use.
The method
utilises a die cut dumb-hell shaped foam specimen which is symmetrically
clamped by both ends on a testing machine. The machine stretches the specimen
and the load and elongation are recorded
on rupture.
TENSILE STRENGTH
Is the
maximum force required to break the test piece, divided by its original cross sectional area. It is
expressed in kPa.
ELONGATION
The change in gauge length of the test piece at the
time of break, expressed as a PERCENTAGE
of its original gauge length.
TEAR RESISTANCE
The
resistance to tear is determined as the force required to propagate a tear in a
pre-cut test piece. It is measured by the trouser tear method and is expressed
in N /m.
RESILIENCE
Resilience is a measure of the springiness of a foam. The more resilient a foam, the more comfortable it is for seating. Resilience is measured by dropping a steel ball onto a foam sample
and measuring the rebound.
CELL COUNT
The cell
size or cell count is an important property as the physical properties of a
flexible foam may vary with changes in cell count. Cell counts are determined
on a cut, plain foam surface using a counting glass.
The
cell counts of reticulated foam are determined by measuring the pressure drop of an air flow through the foam.
POROSITY
In normal
foam, a thin membrane or skin interconnects many of the cells. These
restrict the passage of air and change
performance characteristics depending on
end use. For example, the cell structure can be opened up to reduce closed cells and give better resilience performance. The porosity is normally measured by recording the volume of air
which can be passed through the foam.
AS2281
CLASSIFICATION
The
Australian Standard AS2281-1979 11 Flexible Cellular Polyurethane for Seat
Cushioning and Bedding 11 sets out the requirements (or recommendations) for
the selection of a flexible cellular polyurethane foam for use in seat
cushioning, bedding and similar applications on the basis of foam density and
hardness.
In this
specification:
Conventional
foams are designated Type A
High resilience foams are designated Type B
Reconstituted foams are designated Type C
Additionally
Type A foams
(conventional resilience foams) are sub classified as Normal (N) or Heavy Duty (H) on the basis of density. Type B and Type C foams are classified as Class H.
The Type A,
Type B and Type C foams are then graded
into 13 grades ranging from 00 (softest) to 11 (firm)
according to their hardness.
GRADES AND
DENSITIES OF FLEXIBLE CELLULAR POLYURETHANE |
|||||
|
|
Minimum Density, kg/m3 |
|||
Grade |
40% |
Type A |
Type B |
Type C |
|
Indentation
Force on Deflection |
Class N |
Class H |
Class H |
Class H |
|
00 |
25 |
15 |
22 |
22 |
40 |
0 |
45 - 65
|
16 |
25 |
25 |
40 |
1 |
60 - 90
|
17 |
28 |
28 |
45 |
2 |
85 - 115 |
20 |
30 |
30 |
45 |
3 |
105 - 145 |
23 |
35 |
35 |
50 |
4 |
145 - 180
|
27 |
35 |
35 |
50 |
5 |
170 - 220
|
31 |
35 |
35 |
55 |
6 |
210 - 270
|
31 |
35 |
35 |
55 |
7 |
260 - 330
|
31 |
35 |
35 |
60 |
8 |
320 - 400
|
31 |
35 |
35 |
65 |
9 |
380 - 480
|
31 |
35 |
35 |
70 |
10 |
460 - 580
|
31 |
35 |
35 |
75 |
11 |
560 - 720
|
31 |
35 |
35 |
80 |
(Other properties such as tensile strength, elongation at break, compression
set and other important performance. related characteristics are usually specified at a level which can be
met by several grades of foam.)
The AS2281 specification lists recommendations for the selection of the most suitable foam grade and thickness for a nominated cushioning application.
INDUSTRIAL
FOAM GRADING SYSTEM
Dyman Foams
and their associate companies offer in excess of 50 grades of various foam
types, many of which do not comply with
the requirements for AS2281 classification. To enable our customers to specify
and to select the correct foam type and grade for their particular application,
we have, in conjunction with other foam manufacturers, adopted an industrial grading or a standard system of
description for various foam types.
Flexible
polyether types are graded on the basis of density and hardness.
A coding system
is used to denote other foam types and intended applications.
Key to Coding
Prefixes
L - Conventional polyether foam for light duty applications - below the minimum requirements
of AS2281-1979.
N - Conventional polyether foam for normal
duty applications.
H - Conventional polyether foam for heavy
duty applications.
HR - High resilience foam.
C - Reconstituted foam.
F - Filled foam.
U - Carpet underlay.
SS - Sea sponge.
S - Polyester-urethane foam.
SF - Filled polyester urethane foam.
Suffixes
FL - Flame laminable polyether foam.
CM - Combustion modified foams.
D - Densified foam felts.
R - Reticulated foam.
CONVENTIONAL FLEXIBLE FOAMS
These arc
conventional resilience polyether flexible foams and are made with a density
range of 15-40 kg/m3. They are produced in a continuous slab which is cut into smaller manageable blocks and then converted to
various shapes required for upholstery and other applications. Furniture
components are frequently cut separately and then fabricated together.
Grading
Flexible
polyether polyurethane foams are graded by utilising their density (kg/m3),
Indentation Force on Deflection (50mm IFD 40% ), value expressed in Newton (N),
because these are the characteristics which broadly define their cost and
determine whether they are likely to be satisfactory in service conditions.
Conventional
flexible foams are graded into three main types:
Light Duty Polyether (L)
Normal Duty Polyether (N)
Heavy Duty Polyether (H)
LIGHT DUTY POLYETHER (L)
Grade |
Colour |
Core |
5Omm |
|
|
|
Density |
IFD |
Indentation |
Resilience |
Typical Uses |
||
kg/m |
40%N |
Factor |
% |
|
||
L15-100S |
White |
15.5-16.5 |
85-115 |
1.75 |
50 |
Utility grade |
|
|
|
|
|
|
|
L19-130S |
Mid |
19-20 |
115-145 |
1.75 |
40 |
Overlays,
bed settees |
|
grey |
|
|
|
|
|
L24-160S |
Pink |
24-25 |
145-175 |
1.75 |
40 |
General
upholstery |
|
|
|
|
|
|
|
L27-200
|
Pale |
27.5-28.5 |
170-210 |
1.75 |
45 |
Dining
chairs, auto uses |
|
green |
|
|
|
|
|
These foams
are made in densities varying from 13-27 kg/m3 - and an indentation factor
1.75, together with a resilience figure of 40-50%. These foams have a
fairly light fresh feel. They do not meet the requirements for AS2281-1979 classification and are
intended for light duty and specialised applications.
(Please note
a low density foam of a specific hardness will allow the foam component to perform a particular function for a
relatively short period only. High density foams must be considered when the
products long term durability is to be considered.)
NORMAL DUTY POLYETHFR (N)
|
|
Class
|
Core
|
5Omm
|
Indentation
|
Resilience
|
|
Grade
|
Colour
|
AS2281
|
Density
|
IFD
|
Factor
|
%
|
Typical Uses
|
|
|
-1979
|
kg/m3
|
40%N
|
|
|
|
N 15-60S
|
White
|
N
|
15-16
|
50-70
|
1.75
|
40
|
Soft pillows,
|
|
|
|
|
|
|
|
quilting
|
|
|
|
|
|
|
|
|
N20-100S
|
White
|
N
|
20-21
|
85-115
|
1.75
|
40
|
Back
|
|
|
|
|
|
|
|
cushioning,
|
|
|
|
|
|
|
|
quilting
|
|
|
|
|
|
|
|
|
N23-l30S
|
Pale
|
N
|
23-24
|
110-150
|
1.75
|
40
|
General purpose
|
|
grey
|
|
|
|
|
|
upholstery
|
|
|
|
|
|
|
|
|
N29-400S
|
Dark
|
N
|
29-30
|
350-450
|
1.85
|
20
|
High load bearing,
|
|
grey
|
|
|
|
|
|
Carpet underlay
|
|
|
|
|
|
|
|
|
H31-320S
|
Cream
|
N
|
31-32
|
280-350
|
1.75
|
20
|
High load bearing,
|
|
|
|
|
|
|
|
speciality foam
|
Comply with the requirements for an AS2281-1979 classification as Type A Class N foams. They are available with
a density range of 15-31 kg/m3 and a
resilience figure of 40-55%.
PREMIUM RANGE (5 YEAR GUARANTEE)
|
|
Class |
Core |
5Omm |
Indentation |
Resilience |
|
Grade |
Colour |
AS2281 |
Density |
IFD |
Factor |
% |
Typical Uses |
|
|
-1979 |
kg/m3 |
40%N |
|
|
|
28-80
|
Yellow
|
H |
27-28 |
85-115 |
1.75 |
40 |
Back |
|
|
|
|
|
|
|
cushioning |
|
|
|
|
|
|
|
|
H30-100S |
Yellow |
H |
30-31 |
85-115 |
1.85 |
50 |
Seat cushions |
|
|
|
|
|
|
|
|
H30-130S |
White
|
H |
30-31 |
110-150 |
1.75 |
40 |
Seat cushions |
|
|
|
|
|
|
|
mattresses |
PREMIUM RANGF (10 YEAR
GUARANTEE)
|
|
Minimum |
Hardness |
|
Grade |
Colour |
Density |
Range 5Omm |
Typical Uses |
|
|
kg/m3 |
IFD 40%N |
|
35-l10
|
Purple
|
35 |
100+-15
|
General
purpose seating |
|
|
|
|
|
35-130S |
Light
|
35 |
130+-20
|
General
purpose upholstery |
|
Blue
|
|
|
|
|
|
|
|
|
35-200S |
Dark |
35 |
200+-30
|
Transport seating |
|
Blue |
|
|
|
CM5 (10 YEAR GUARANTEE)
|
|
Minimum |
Hardness |
|
Grade |
Colour |
Density |
Range 5Omm |
Typical Uses |
|
|
kg/m3 |
IFD 40%N |
|
HR36-100 CM5 |
Bright
|
36 |
100+-15
|
Premium mattress and cushioning |
Green
|
||||
|
|
|
|
|
HR36-130 CM5 |
Bright
|
36 |
130+-15
|
Premium cushioning |
|
yellow |
|
|
The Platinum CM Range is a system using high resilience polyol and a solid
melamine fill for combustion modification. There are currently no AS2281-1979
classifications for combustion modified filled HR foams. Under AS2281-1979 HR
foams need a resilience performance of over 60% as well as other test criteria to
qualify. Most Platinum CM grades still
pass this test but melamine filling does reduce the performance in some grades. Here we have called Platinum CM a
CMHR foam because it is using a combustion modified HR technology where a new
standard will eventually apply.
Conventional Polyester-Urethane Foams
Polyester
foam was the first type of polyurethane foam to be used in upholstery and
transport seating but it now has been almost replaced in these applications
by the cheaper and more resilient polyether foams. Production of polyester foams continues
for specialised applications, textile
laminating, packaging, sound absorption and various other technical applications.
They are also used in the padding and insulating of clothes, eg. shoulder pads.
Polyester
foams are characterised by their high hardness and tensile strengths compared to polyether foams and are made in a wide range of cell counts and
densities which depend on the application requirements.
Grading
Polyester
foams, unlike polyethers, are not graded
by the density and hardness but by their density and cell count. This is because
the main uses are in acoustics, filtration, or as an absorption medium where performance is dependent upon the cell
count.
FOAM APPLICATIONS
Foam has many applications
General
Air Filters
Absorbs Sound
Anti Surge Mitigator
Carpet Underlay
Cushions, seats, hacks, overlays, head
rests etc .
Liquid Filters
Mattresses Single
Double
Queen
Cot
Bassinette
Pillows
Reservoirs
Seals
Sponges
Wicks
Specialty
Numerous
applications.
Polyester foam is typically used for -
Flame lamination to fabric for apparel and is also used to laminate light fabrics together to give bulk to the final fabric
Gaskets and seals
Toys - soft varieties
Filter material - Reticulated foam
Decorative seat padding in conjunction
with either vinyl or synthetic yarn fabrics
Artificial flowers
Acoustic facings for loudspeaker enclosures and industrial noise control
Packaging
Polyether foam is by far the most widely used foam in Australia. Examples of its versatility of application are -
Mattresses - domestic and recreational use
Overlay for innerspring mattresses
Adhesive laminated to fabric for such applications as soft feel toilet bags, or sewn
decorative padding for furniture or automotive seating
Inner soles for footwear
Foam blankets
Pillows and scatter cushions
Carpet underlay
Acoustic applications
Protective padding and packaging
Moulded complete lounge furniture
Profile cut and fabricated lounge
furniture
Moulded automotive seating
Fabricated automotive seating
Book cover padding in stationery
industry
Bath sponges
Public auditorium seating
Public transport seating
Reconstituted foam is manufactured by crumbing either polyether or polyester foam
into particular size particles. The
particles are then bonded to form a dense foam. This product finds particular application in
Seating, where a very firm seat is
required
Reinforcement for fabricated seat
padding in domestic and automotive applications
Carpet underlay
Packaging
Sporting mats
This product is currently not offered by Dymanfoams.
Lamination
Polyurethane
foams can be bonded to a variety of materials either by the use of adhesives or
the "flame lamination" technique. The foam is peeled into foils of
say 1.5 to 6mm thick for use in clothing, car trim and footwear etc. The
density required for a given laminating application is a compromise between
durability and price. For textile laminates which are subject to high service stress, foams of
density 26 kg/m3. higher are used. Lower densities are used for laminates which undergo less service stress.
The
appearance of laminating grade foams is much more important than it is
for upholstery foams. The control of
cell size, porosity and uniformity and absence of short holes is critical to
laminating processes, especially name
lamination.
In the flame
lamination process, the surface of the foam is heated usually by a gas name
until the surface layer fuses and becomes soft and tacky. It is then immediately bonded to the fabric.
Grade S21/70
and Grade S26/80 (formerly EF200 and EF280 respectively) are the recommended polyester laminating grades but the polyether grade N26-140FL is also intended
for name laminating. However, polyesters are generally selected because of the
resistance to damage whilst being
cleaned with solvents and because the laminating parameters are not as critical.
In adhesive
bonding the adhesive is applied to the surface of the foam to bond the fabric
to the foam.
Foam linings for textiles helps to dimensionally stabilise the textile and provide a high insulating quality that allows the
laminate to breathe. It also provides
excellent crease resisting properties.
Various plastics,
paper, metallic foils can be bonded to
polyurethane foam for application in the
footwear, automotive and application fields.
Packaging
Flexible
polyurethane foam is ideal for packaging applications because it exhibits the
following:
a) An outstanding shock absorbency over a
wide stress range
b) Good insulating characteristics
c) Unaffected by heat and cold (-400C to 1200C)
d) Resistant to mildew, rot and vermin
e) It can be easily shaped and fabricated
and is available in thin sheets
f) Offers advantages of maximum protection
with a minimum of weight and volume
Both polyether and polyester types can be
utilised depending on the end use but
the advantage of using polyester foams
in padding and packaging applications lies in its initial high resistance to
compression and its high energy
absorption.
Thin sheets
of polyester foam (say 1.5mm) can be used as a protective wrapping for packaging fragile items such as
glassware and china.
Acoustic
Any structure that is open and which will allow sound to enter and to vibrate internal cells or fibres will absorb acoustical energy. As the sound wave enters the structure the
pressure pulse - of the acoustical wave causes the cell to. vibrate. The resultant mechanical movement of the
strands dissipate the energy which is released as heat (an infinitesimal increase in temperature).
(The
capacity of a material to absorb sound rather than reflect it is expressed as
the Sound Absorption Coefficient). For example, if a material absorbs 50% of
incident sound energy at a certain frequency, then it has a sound absorption
coefficient at 0.50 at that frequency.)
Absorption materials include fibrous glass, rockwall carpets, drapes, furnishings even people . and clothing. The one unifying factor is the
necessity to a1low the acoustical wave
to penetrate to the interior of the material where it can interact with the
cellular structure.
All flexible
cellular foams arc absorption materials, but the acoustical properties of these will vary due to the physical characteristics of the foam itself. Some of these major variables include cell structure, thickness, permeability and surface treatment.
Permeability
is the ability to allow the passage or
the air and can be measured as the pressure drop exhibited by a gas moving through the foam. It generally increases with an increase in the cell size. However, permeability is also affected by the surface
nature of the cell and is greatly influenced by the number of closed cells. As
a result of the way they are manufactured non - reticulated foam normally. have a thin membrane or skin interconnecting many of the cells. These closed cells restrict the passage of the air and decrease the
permeability of the foam.
Although
this characteristic would seem ideal for blocking sound TOO MANY closed cells will prevent the acoustical energy
from entering the foam where it can be dissipated by the ribs that make up the
cell structure.
It should be
noted that as material thickness increases, reticulated foams have increased absorption characteristics and in
thicknesses of 50mm or greater are better than non-reticulated foam.
From a
practical or engineering point of view, perhaps the most important attribute of
foam is that it can be manufactured
consistently with a specific cell size structure and cell size. This allows the
material to be selected either to transmit or attenuate sound.
Foam can be
cut to conform to specific shapes and is uniform m thickness and surface characteristics which leads to reproducible acoustic properties.
Additionally,
foam does not shred or produce fibrous dust into the environment or produce debris that could
interfere with the operation of electrical contacts.
The
manufacturing techniques used at Dyman Foams are controlled so that the
variables such as permeability, cell size and thickness that affect the
absorption properties at different frequencies ensure that the acoustic foam
range have good predictable acoustic characteristics.
This is
demonstrated by comparing the attached statistical absorption coefficient
charts.
Figure 1
shows an actual acoustical absorption of Dyman Foams grade S32/70 CM (EF570) -
a combustion modified non-reticulated foam. This sample is on the "fine" side of the
manufacturing specification.
Figure 11 -
same foam type S32/70 CM but on the "coarse" side of the
manufacturing specification.
ACOUSTIC FOAMS
Product |
Function |
Application |
S28/70 CM
|
Sound Absorber |
General use - UL94
Classification HF1 |
These base
foams are modified to
a) Obtain a desired acoustical property
b) Give the foam protection against a
particular environment
c) Give some decorative effect.
Solid Backing
Although
foam requires certain acoustical properties for optimum absorption efficiency, the most critical requirement is the need for a solid impermeable
backing. Without such a backing, sound passes through with only moderate attenuation. Experience has shown that unbacked foam wrapped around a pipe, or draped over machinery, is not effective in dissipating noise.
However, a
solid backing requires .the. sound to enter the foam, reflect off the backing
and come out the same way it went in. The attenuation provided by this reflection technique is more than double that of an equal
thickness of unbacked foam. Although
the attenuation process provided by the backing is not completely understood, it is believed that the incoming and. outgoing . sound
signals may he out of phase and thus, may tend to cancel each other.
Equipment housings (if they are heavy enough) can act
as solid hacking for foam linings and in such applications for foam, reduces
the reverberation build up of noise
inside the enclosure.
However,
openings in an enclosure tend to minimise the silencing effect of the foam because any sound that "sees" the
opening will escape. Such openings or holes in an enclosure are far more harmful than the thinners of the walls in terms of letting sound escape. Thus it does not make sense to specify the walls of an acoustic enclosure to
be constructed of heavy tight materials (ic.
timber, masonry, steel) if there are a number of openings through which the sound can pass through.
In such applications baffles can he used to prevent the sound from having a clean path out of the enclosure.
Protective Facings
Conversely
as much as a solid hacking attenuates sound, a protective face or an acoustic foam may effect the
absorption efficiency, particularly at medium and high frequencies (eg. vinyl, mylar).
Such facings
reduce the permeability of the foam and restrict the passage of acoustical energy into the foam cells
One of
the many techniques used to give foam protective properties. that laminated films have, eg. scuff resistance, is to heat
emboss the foam surface.. This compacts the surface pores to produce a tough, easily cleaned surface that does not markedly degrade acoustical properties.
Other
techniques include flame bonding a protective facing to the foam. This technique involves the melting of the foam
surface which then acts as its own adhesive to hold the facing. Unlike adhesive
boding (when an excess of adhesive is used) the flame bonding does not form a
barrier between the foam and protective facing which if it has a sufficient
number of perforations, will allow the
acoustical energy to enter the foam and be absorbed.
Passing Sound
The
permeability of foam also makes it a good transmission medium for sound. Basically, if foam is used as an
acoustically "clear" material, all that the sound should see are holes and cell ribs of the foam structure. The more holes, the more early the sound passes through. Therefore the requirement for sound transparency is for large cells.
The most
suitable foams for such applications arc the open cell reticulated types which
produce little off-axis deflections of the sound waves.
These
deflections which produce major distortions of the sound and attenuate highs
(above 500 HZ), are most prominent in open cell non-reticulated foams because the
membranes between the cells cause the sound waves to bounce and scatter away
from the main transmission axis.
Speaker and
microphone cores arc major applications
for acoustically transparent foams - the
foam not only provides acoustic transparency, but additionally protects the
components from physical damage, keeps out dust and with microphones acts as a
wind sock. Common foam thickness for
acoustically transparent foams range from 6mm to 50mm. The thicker foams are to provide distinctive
sculptural effects and also to hide components such as speaker cores etc.
For such
uses the foam normally has 30 cells per 25mm.
Larger cell
sizes would not be effective in hiding the speaker shadow.
Thermal Insulation
Flexible
polyurethane foam has good thermal insulating characteristics. The thermal conductivity factor "K" is of the order of 0.033 W/mK at densities around 30 kg/m3. This value is dependent on the permeability of the foam. (The lower the
value of the K factor, the better the insulation properties.) The 11exible foam
(both polyester and polyether) should be scaled to
prevent moisture penetration as moisture will reduce the thermal insulation
properties.
Applications include gap filling, vibration protection and
window sealings.
Medical
Flexible polyurethane foam does not absorb x-rays and is an ideal support material for body parts during x-ray procedures.
Urethane foams arc also used as elastic
bandages which utilise the self-ventilating
property of the product, although
contact with open wounds should be avoided.
INDUSTRY
BACKGROUND
The
history of polyurethane foam goes back
to 1848 when the basic urethane reaction was reported.
It involved
a reaction between an isocyanate and a hydroxy compound. The significance of
this discovery was confined to laboratory reactions for the next ninety years.
The next
historical landmark occurred in 1937, when Dr Otto Bayer and co-workers in
Germany discovered the polymerisation reaction for a family of organic chemical
compounds known today as polyurethanes. The objective at that time, was to
develop a polyester based urethane to compete with nylon.
The advent
of World War II, and the .subsequent shortages of rubber in Germany, hastened
the development of urethane materials in such applications of fibres,
adhesives, surface coatings, elastomers and rigid foams. This technology became
generally known at the end of the war and stimulated development in the United
States, Britain and elsewhere.
In 1952, Bayer
laboratories developed flexible polyurethane, based on the principle of the
1937 discovery.
In 1953 the
preparation of polyurethane foam in USA was announced.
The unique
reaction of polyurethane materials required the development of previously unavailable equipment and
techniques. Several companies entered this new field and the commercial
production of this new product began.
Initially,
all of the work in flexible and rigid foam was based on the reaction of a
polyester compound and an diisocyanate. Thus the first urethane foams were of
polyester type.
Several
shortcomings quickly came to light. These foams did not have the most desirable comfort characteristics and
also tended to deteriorate in a
humid environment. Furthermore, they were relatively expensive
to produce.
It was not
until 1957, with the introduction of urethane grade polyether polyols, that the
true potential of the 11exible polyurethane industry was realised. Not
only had the polyether urethane a cost
advantage over the polyester type, but they offered far superior physical
properties along with better cushioning characteristics.
WHAT IS SO DIFFERENT ABOUT POLYURETHANE FOAM?
The
outstanding characteristic of polyurethane foam is its versatility. The devised
end-use properties can he built into the urethane foam. This means that it is
possible to produce a high resilience foam for comfort cushioning and a low
resiliency foam that is dead enough to absorb impact without bouncing the shock
back to an object. Rigid urethane foams as hard as wood, can also he made for construction and insulation applications.
Thin walled refrigerators and freezers are insulated with urethane
foam.
HOW IS URETHANE FOAM MADE?
Making
polyurethane foam can be compared to making a cake without an oven. The ingredients - polyol, diisocyanate,
catalysts and other components are mixed as they are poured from a mixing head
under precise' automatic control, into a baking pan. which consists of a paper lined conveyor system (continuous
mould).
The reaction
begin immediately, generating its own heat and releasing carbon dioxide which bubble up and causes the "cake" (urethane foam) to rise.
By changing the chemical ingredients and processing conditions, foams of different cell structures, density, hardness and other devised properties can be obtained.
The
chemicals include a polyol (polyether or polyester) and TDI (Toluene.
Diisocyanate) which interact to form the urethane polymer; water which mixes
with the TDI to generate the gas that inflates the foam; catalysts which
control the reaction rate; a stabiliser which helps the foam set in the desired
shape. Other additions which can be added include pigments, fire retardants, sanitising agents etc.
These
chemicals are stored in tanks and pumped to the foam machines through pipewort,
hoses, exchangers and control devices.
There are
two types of foaming machines in use by Dyman/Joyce Group. In the machines sited at Sydney, Brisbane and
Adelaide, the blended chemicals are dispensed from a
mixing head onto a moving paper-lined
conveyor set-up on which it expands and sets. These machines originally
produced conventional crown topped continuous blocks of foam that were shaped
like loaves of bread up to two metres wide and almost one metre high.
However,
several years ago, the machines were fitted with the Planiblock Square Block
System which allows for the production of foam blocks with flat tops which do
not require the wasteful trimming of the rounded top block. The Planiblock system uses an additional top paper which is applied
just beyond the point of mix lay down. An arrangement of platens (skis) with adjustable counter balances, applies just sufficient pressure on
the rising foam to prevent the formation of the crown top with the minimum
effect on foam density.
The Maxfoam
machine, sited at Melbourne and a smaller type machine in Perth, make a
rectangular foam block of very uniform density. The Maxfoam machine and the Perth machine are different to the other
machine types in the Group, in that the foam mixture feeds into the bottom of a
trough. The foam mixture begins foaming up ..... covered inclined conveyor. Then as the rising foam moves out, the bottom paper drops and the
foam expands downwards instead of
rising. This accounts for the flat top on the bun and its uniform density.
Polyester
polyurethane flexible foams are produced at Liverpool only and are made in the
round top configuration.
Both machine
types require about one and a half hours
or more to set-up before even one block of foam can be produced. When the machine is operating, it dispenses hundreds of dollars worth of chemicals per
minute, so mistakes are costly. Additionally, the starting and finishing block of each run are usually discarded because they are not homogeneous, the correct shape etc.
Because we
make foam in a variety of grades, cell sizes and colours to meet our customer
requirements, orders and foam machine times must be scheduled with an emphasis
approaching maximum efficiency. Obviously the most efficient set-up would be
one in which the foam machines would foam all day on one
set-up, producing only one grade of foam.
The Maxfoam/Varimax
System for Flat-topped Blocks
The
Planiblock/Hennecke System for Flat-topped Blocks
Two separate
areas are used for foam block storage.
a) Fresh Block Curing Area
This area usually has reasonable
separation from other buildings and is used to store freshly made blocks. The heat of
reaction reaches its maximum about two hours after manufacture. The blocks are usually left in this area for 24 hours-.
b) Long
Term Storage
This area is used for long term storage of blocks until needed for further conversion or delivery.
FOAM BLOCK CONVERSION
The foam
blocks are converted into intermediates and finished products such as smaller
blocks, sheets, for fabrication components, rolls etc. by utilising one or more
of the following:
Peeling
Splitting
Profile Cutting
Fabricating
Reticulating
Impregnating
Crumbing
Rebonding
Dyman Foams Pty Ltd 105
Robinson Road
GEEBUNG Q 4034
Phone: (07) 3865 1400 Fax: (07) 3865 1757